Review for metal and organocatalysis of heterocyclic C-H functionalization
National Research Centre, Photochemistry Department, Industrial Chemical Division, Cairo, Egypt.
Review Article
World Journal of Advanced Research and Reviews, 2021, 09(01), 001-030
Article DOI: 10.30574/wjarr.2021.9.1.0071
Publication history:
Received on 01 October 2020; revised on 21 December 2020; accepted on 25 December 2020
Abstract:
Over the last few decades, significant efforts have been put forth towards the C−H bond group functionalization by transition-metalcatalysis and organocatalysis. Several efficient strategies to convert C-H bond to other groups C-C, C-N, C-O bonds have been implemented. The most attractive C-H bond functionalization was the C-H heterocyclic compounds activation that is practical method in organic synthesis. The new C–C, C–N and C–O bond as formed from the C-H bond activation by two diverse ways metal catalysis and/or organocatalysis. The most important is the synthesis of new bioactive heterocyclic compounds by easy and less expensive materials. In this review, we will cover most of the syntheses of heterocyclic derivatives by the functionalization of C-H bond in metal and organocatalytic reagents.
Keywords:
Heterocyclic; C-H activation; Metal catalysis; C-H activation; C-H activation organocatalysis.
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